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| 02.03.1991 | Cádiz CF | - | Real Madrid | 1:0 (1:0) | ||
| Barcelona | - | Tenerife | 1:0 (1:0) | |||
| Sevilla | - | Betis | 3:2 (2:1) | |||
| 03.03.1991 | Real Sociedad | - | Real Oviedo | 3:1 (2:1) | ||
| Mallorca | - | Valencia | 0:1 (0:0) | |||
| CD Logroñés | - | Real Burgos | 0:0 (0:0) | |||
| CD Castellón | - | Valladolid | 4:2 (1:1) | |||
| Atlético | - | Athletic | 2:0 (0:0) | |||
| Sporting | - | Osasuna | 1:1 (1:1) | |||
| Zaragoza | - | Espanyol | 1:1 (1:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 24 | 18 | 4 | 2 | 52:20 | 32 | 40:8 |
| 2 |
|
Atlético | 24 | 13 | 9 | 2 | 35:10 | 25 | 35:13 |
| 3 |
|
Osasuna | 24 | 11 | 9 | 4 | 31:19 | 12 | 31:17 |
| 4 |
|
Real Madrid | 24 | 12 | 4 | 8 | 37:22 | 15 | 28:20 |
| 5 |
|
Sevilla | 24 | 12 | 4 | 8 | 30:26 | 4 | 28:20 |
| 6 |
|
Sporting | 24 | 9 | 8 | 7 | 31:24 | 7 | 26:22 |
| 7 |
|
Valencia | 24 | 10 | 6 | 8 | 30:27 | 3 | 26:22 |
| 8 |
|
CD Logroñés | 24 | 9 | 7 | 8 | 17:18 | -1 | 25:23 |
| 9 |
|
Real Oviedo | 24 | 8 | 9 | 7 | 18:27 | -9 | 25:23 |
| 10 |
|
Real Burgos | 24 | 6 | 10 | 8 | 18:17 | 1 | 22:26 |
| 11 |
|
Real Sociedad | 24 | 6 | 10 | 8 | 22:27 | -5 | 22:26 |
| 12 |
|
Zaragoza | 24 | 7 | 7 | 10 | 25:27 | -2 | 21:27 |
| 13 |
|
Espanyol | 24 | 7 | 7 | 10 | 25:28 | -3 | 21:27 |
| 14 |
|
Athletic | 24 | 9 | 3 | 12 | 22:29 | -7 | 21:27 |
| 15 |
|
CD Castellón | 24 | 5 | 10 | 9 | 18:25 | -7 | 20:28 |
| 16 |
|
Mallorca | 24 | 7 | 6 | 11 | 21:29 | -8 | 20:28 |
| 17 |
|
Valladolid | 24 | 5 | 9 | 10 | 24:31 | -7 | 19:29 |
| 18 |
|
Tenerife | 24 | 7 | 4 | 13 | 21:40 | -19 | 18:30 |
| 19 |
|
Cádiz CF | 24 | 4 | 9 | 11 | 16:26 | -10 | 17:31 |
| 20 |
|
Betis | 24 | 4 | 7 | 13 | 22:43 | -21 | 15:33 |
