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| 01.04.2006 | 20:00 | Zaragoza | - | Villarreal | 0:1 (0:1) | |
| 20:00 | Real Sociedad | - | Málaga | 3:0 (1:0) | ||
| 22:00 | Barcelona | - | Real Madrid | 1:1 (1:1) | ||
| 02.04.2006 | 17:00 | Valencia | - | Cádiz CF | 5:3 (3:1) | |
| 17:00 | Mallorca | - | Espanyol | 0:0 (0:0) | ||
| 17:00 | Alavés | - | Athletic | 0:0 (0:0) | ||
| 17:00 | Osasuna | - | Getafe | 0:4 (0:2) | ||
| 17:00 | Deportivo | - | Real Racing | 2:0 (1:0) | ||
| 19:00 | Atlético | - | Celta | 0:3 (0:0) | ||
| 21:00 | Betis | - | Sevilla | 2:1 (2:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 31 | 21 | 6 | 4 | 70:27 | 43 | 69 |
| 2 |
|
Real Madrid | 31 | 17 | 7 | 7 | 56:28 | 28 | 58 |
| 3 |
|
Valencia | 31 | 15 | 11 | 5 | 44:28 | 16 | 56 |
| 4 |
|
Osasuna | 31 | 17 | 4 | 10 | 41:37 | 4 | 55 |
| 5 |
|
Celta | 31 | 16 | 3 | 12 | 34:29 | 5 | 51 |
| 6 |
|
Sevilla | 31 | 15 | 6 | 10 | 39:32 | 7 | 51 |
| 7 |
|
Deportivo | 31 | 14 | 7 | 10 | 42:37 | 5 | 49 |
| 8 |
|
Villarreal | 31 | 12 | 12 | 7 | 41:30 | 11 | 48 |
| 9 |
|
Atlético | 31 | 11 | 10 | 10 | 40:32 | 8 | 43 |
| 10 |
|
Getafe | 31 | 12 | 7 | 12 | 44:40 | 4 | 43 |
| 11 |
|
Zaragoza | 31 | 9 | 14 | 8 | 39:39 | 0 | 41 |
| 12 |
|
Betis | 31 | 9 | 9 | 13 | 29:41 | -12 | 36 |
| 13 |
|
Athletic | 31 | 8 | 10 | 13 | 32:38 | -6 | 34 |
| 14 |
|
Espanyol | 31 | 8 | 9 | 14 | 30:46 | -16 | 33 |
| 15 |
|
Real Racing | 31 | 7 | 12 | 12 | 26:35 | -9 | 33 |
| 16 |
|
Alavés | 31 | 7 | 11 | 13 | 31:45 | -14 | 32 |
| 17 |
|
Mallorca | 31 | 7 | 11 | 13 | 29:45 | -16 | 32 |
| 18 |
|
Real Sociedad | 31 | 9 | 4 | 18 | 39:57 | -18 | 31 |
| 19 |
|
Cádiz CF | 31 | 6 | 9 | 16 | 24:43 | -19 | 27 |
| 20 |
|
Málaga | 31 | 5 | 8 | 18 | 30:51 | -21 | 23 |
