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| I | Barcelona | - | Manchester United | 2:2 (0:0) | ||
| V | Manchester United | - | Barcelona | 2:1 (0:1) | ||
| I: 16.02.2023 18:45 | V: 23.02.2023 21:00 | Campeones: Manchester United | ||||
| I | Shakhtar Donetsk | - | Rennes | 2:1 (2:0) | ||
| V | Rennes | - | Shakhtar Donetsk | 4:5 (0:0, 1:0, 2:1) pn. | ||
| I: 16.02.2023 18:45 | V: 23.02.2023 21:00 | Campeones: Shakhtar Donetsk | ||||
| I | AFC Ajax | - | 1. FC Union Berlin | 0:0 (0:0) | ||
| V | 1. FC Union Berlin | - | AFC Ajax | 3:1 (2:0) | ||
| I: 16.02.2023 18:45 | V: 23.02.2023 21:00 | Campeones: 1. FC Union Berlin | ||||
| I | RB Salzburg | - | Roma | 1:0 (0:0) | ||
| V | Roma | - | RB Salzburg | 2:0 (2:0) | ||
| I: 16.02.2023 18:45 | V: 23.02.2023 21:00 | Campeones: Roma | ||||
| I | Juventus | - | Nantes | 1:1 (1:0) | ||
| V | Nantes | - | Juventus | 0:3 (0:2) | ||
| I: 16.02.2023 21:00 | V: 23.02.2023 18:45 | Campeones: Juventus | ||||
| I | Sporting CP | - | FC Midtjylland | 1:1 (0:0) | ||
| V | FC Midtjylland | - | Sporting CP | 0:4 (0:1) | ||
| I: 16.02.2023 21:00 | V: 23.02.2023 18:45 | Campeones: Sporting CP | ||||
| I | Bayer Leverkusen | - | Mónaco | 2:3 (0:1) | ||
| V | Mónaco | - | Bayer Leverkusen | 3:5 (1:2, 2:3, 2:3) pn. | ||
| I: 16.02.2023 21:00 | V: 23.02.2023 18:45 | Campeones: Bayer Leverkusen | ||||
| I | Sevilla | - | PSV | 3:0 (1:0) | ||
| V | PSV | - | Sevilla | 2:0 (0:0) | ||
| I: 16.02.2023 21:00 | V: 23.02.2023 18:45 | Campeones: Sevilla | ||||
