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| 25.05.1991 | Real Madrid | - | Sporting | 2:1 (2:0) | ||
| Valencia | - | Athletic | 2:1 (2:0) | |||
| 26.05.1991 | Espanyol | - | Osasuna | 0:1 (0:0) | ||
| Real Sociedad | - | CD Castellón | 1:1 (1:0) | |||
| Zaragoza | - | Mallorca | 2:2 (0:2) | |||
| Betis | - | Tenerife | 1:1 (0:1) | |||
| Real Oviedo | - | Atlético | 3:0 (0:0) | |||
| CD Logroñés | - | Barcelona | 0:2 (0:1) | |||
| Valladolid | - | Real Burgos | 1:0 (0:0) | |||
| Cádiz CF | - | Sevilla | 2:1 (1:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 36 | 25 | 6 | 5 | 74:32 | 42 | 56:16 |
| 2 |
|
Atlético | 36 | 17 | 13 | 6 | 51:22 | 29 | 47:25 |
| 3 |
|
Osasuna | 36 | 14 | 15 | 7 | 42:32 | 10 | 43:29 |
| 4 |
|
Real Madrid | 36 | 18 | 6 | 12 | 59:37 | 22 | 42:30 |
| 5 |
|
Sporting | 36 | 14 | 12 | 10 | 46:37 | 9 | 40:32 |
| 6 |
|
Real Oviedo | 36 | 12 | 15 | 9 | 33:35 | -2 | 39:33 |
| 7 |
|
Valencia | 36 | 14 | 10 | 12 | 42:39 | 3 | 38:34 |
| 8 |
|
Sevilla | 36 | 14 | 8 | 14 | 43:45 | -2 | 36:36 |
| 9 |
|
Valladolid | 36 | 11 | 13 | 12 | 37:39 | -2 | 35:37 |
| 10 |
|
Real Sociedad | 36 | 11 | 13 | 12 | 39:44 | -5 | 35:37 |
| 11 |
|
Real Burgos | 36 | 9 | 16 | 11 | 30:27 | 3 | 34:38 |
| 12 |
|
CD Logroñés | 36 | 12 | 10 | 14 | 26:34 | -8 | 34:38 |
| 13 |
|
Athletic | 36 | 14 | 6 | 16 | 37:49 | -12 | 34:38 |
| 14 |
|
Tenerife | 36 | 13 | 7 | 16 | 36:51 | -15 | 33:39 |
| 15 |
|
Zaragoza | 36 | 11 | 10 | 15 | 35:38 | -3 | 32:40 |
| 16 |
|
Espanyol | 36 | 11 | 10 | 15 | 36:43 | -7 | 32:40 |
| 17 |
|
Mallorca | 36 | 9 | 14 | 13 | 32:40 | -8 | 32:40 |
| 18 |
|
CD Castellón | 36 | 8 | 11 | 17 | 27:45 | -18 | 27:45 |
| 19 |
|
Cádiz CF | 36 | 6 | 14 | 16 | 27:40 | -13 | 26:46 |
| 20 |
|
Betis | 36 | 6 | 13 | 17 | 37:60 | -23 | 25:47 |
