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| 14.09.1991 | Real Oviedo | - | Real Sociedad | 2:0 (1:0) | ||
| Valencia | - | Real Burgos | 1:1 (0:1) | |||
| Athletic | - | Real Madrid | 1:4 (0:3) | |||
| Barcelona | - | Zaragoza | 3:1 (1:1) | |||
| Osasuna | - | Mallorca | 1:0 (1:0) | |||
| 15.09.1991 | Sevilla | - | Sporting | 2:1 (1:0) | ||
| Tenerife | - | Albacete | 2:3 (1:0) | |||
| Valladolid | - | CD Logroñés | 1:2 (1:2) | |||
| Cádiz CF | - | Deportivo | 1:0 (1:0) | |||
| Atlético | - | Espanyol | 3:0 (2:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Atlético | 3 | 3 | 0 | 0 | 7:0 | 7 | 6:0 |
| 2 |
|
Sevilla | 3 | 3 | 0 | 0 | 8:3 | 5 | 6:0 |
| 3 |
|
Real Madrid | 3 | 3 | 0 | 0 | 6:1 | 5 | 6:0 |
| 4 |
|
Real Oviedo | 3 | 2 | 1 | 0 | 3:0 | 3 | 5:1 |
| 5 |
|
Barcelona | 3 | 2 | 0 | 1 | 7:5 | 2 | 4:2 |
| 6 |
|
Sporting | 3 | 2 | 0 | 1 | 5:4 | 1 | 4:2 |
| 7 |
|
Albacete | 3 | 2 | 0 | 1 | 4:4 | 0 | 4:2 |
| 8 |
|
CD Logroñés | 3 | 2 | 0 | 1 | 4:5 | -1 | 4:2 |
| 9 |
|
Osasuna | 3 | 2 | 0 | 1 | 3:4 | -1 | 4:2 |
| 10 |
|
Tenerife | 3 | 1 | 1 | 1 | 6:4 | 2 | 3:3 |
| 11 |
|
Real Burgos | 3 | 1 | 1 | 1 | 5:3 | 2 | 3:3 |
| 12 |
|
Valencia | 3 | 1 | 1 | 1 | 3:3 | 0 | 3:3 |
| 13 |
|
Cádiz CF | 3 | 1 | 0 | 2 | 2:3 | -1 | 2:4 |
| 14 |
|
Zaragoza | 3 | 0 | 2 | 1 | 2:4 | -2 | 2:4 |
| 15 |
|
Deportivo | 3 | 0 | 1 | 2 | 2:4 | -2 | 1:5 |
| 16 |
|
Mallorca | 3 | 0 | 1 | 2 | 0:3 | -3 | 1:5 |
| 17 |
|
Espanyol | 3 | 0 | 1 | 2 | 1:5 | -4 | 1:5 |
| 18 |
|
Real Sociedad | 3 | 0 | 1 | 2 | 0:4 | -4 | 1:5 |
| 19 |
|
Valladolid | 3 | 0 | 0 | 3 | 1:4 | -3 | 0:6 |
| 20 |
|
Athletic | 3 | 0 | 0 | 3 | 3:9 | -6 | 0:6 |
