| 1. Jornada | 07.08.1999 | RSC Charleroi | - | KRC Harelbeke | 2:1 | ||||
| 2. Jornada | 14.08.1999 | KV Mechelen | - | RSC Charleroi | 2:1 | ||||
| 3. Jornada | 21.08.1999 | RSC Charleroi | - | KVC Westerlo | 1:2 | ||||
| 7. Jornada | 26.09.1999 | Verbroedering Geel | - | RSC Charleroi | 0:0 | ||||
| 14. Jornada | 20.11.1999 | RSC Charleroi | - | Sporting Lokeren | 2:4 | ||||
| 23. Jornada | 13.02.2000 | RSC Charleroi | - | Standard Liège | 1:4 | ||||
| 25. Jornada | 04.03.2000 | Excelsior Mouscron | - | RSC Charleroi | 2:1 | ||||
| 26. Jornada | 12.03.2000 | RSC Charleroi | - | KSK Beveren | 2:3 | ||||
| 27. Jornada | 18.03.2000 | Lierse SK (old) | - | RSC Charleroi | 2:0 |  |
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| 28. Jornada | 25.03.2000 | RSC Charleroi | - | Lommelse SK | 1:1 |
República Centroafricana