| 1. Jornada | 07.08.1999 | RSC Charleroi | - | KRC Harelbeke | 2:1 | ||||
| 2. Jornada | 14.08.1999 | KV Mechelen | - | RSC Charleroi | 2:1 | ||||
| 4. Jornada | 28.08.1999 | Gante | - | RSC Charleroi | 3:2 | ||||
| 5. Jornada | 11.09.1999 | RSC Charleroi | - | KRC Genk | 2:1 | ||||
| 6. Jornada | 17.09.1999 | Standard Liège | - | RSC Charleroi | 1:3 | ||||
| 7. Jornada | 26.09.1999 | Verbroedering Geel | - | RSC Charleroi | 0:0 | ||||
| 8. Jornada | 01.10.1999 | RSC Charleroi | - | Excelsior Mouscron | 2:1 | ||||
| 9. Jornada | 13.10.1999 | KSK Beveren | - | RSC Charleroi | 1:1 |
Croacia