| 2. Jornada | 22.07.2012 | Volyn Lutsk | - | Vorskla Poltava | 1:0 | ||||
| 3. Jornada | 28.07.2012 | Chernomorets Odessa | - | Volyn Lutsk | 0:2 |  |
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| 4. Jornada | 06.08.2012 | Volyn Lutsk | - | Shakhtar Donetsk | 0:4 | ||||
| 5. Jornada | 12.08.2012 | Dinamo Kiev | - | Volyn Lutsk | 4:1 | ||||
| 6. Jornada | 19.08.2012 | Volyn Lutsk | - | Zorya Lugansk | 2:2 | ||||
| 7. Jornada | 26.08.2012 | Dnipro Dnipropetrovsk | - | Volyn Lutsk | 2:1 | ||||
| 8. Jornada | 02.09.2012 | Volyn Lutsk | - | Metalist Kharkiv | 2:1 | |
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| 9. Jornada | 15.09.2012 | FK Illichivets | - | Volyn Lutsk | 0:0 | ||||
| 10. Jornada | 29.09.2012 | Volyn Lutsk | - | Tavriya Simferopol (1958-2014) | 0:1 | |
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| 11. Jornada | 06.10.2012 | Metalurg Zaporizhya | - | Volyn Lutsk | 0:3 | |
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| 13. Jornada | 26.10.2012 | Arsenal Kiev | - | Volyn Lutsk | 1:1 | ||||
| 19. Jornada | 01.03.2013 | Shakhtar Donetsk | - | Volyn Lutsk | 4:1 | |
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| 20. Jornada | 10.03.2013 | Volyn Lutsk | - | Dinamo Kiev | 0:2 | |
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| 21. Jornada | 16.03.2013 | Zorya Lugansk | - | Volyn Lutsk | 3:1 | |
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| 22. Jornada | 31.03.2013 | Volyn Lutsk | - | Dnipro Dnipropetrovsk | 1:1 |  |
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| 24. Jornada | 12.04.2013 | Volyn Lutsk | - | FK Illichivets | 0:2 | ||||
| 25. Jornada | 21.04.2013 | Tavriya Simferopol (1958-2014) | - | Volyn Lutsk | 3:0 | |
Rumania