| 2. Jornada | 17.07.2005 | Zakarpattya Uzhgorod | - | Metalurh Donetsk | 0:0 | ||||
| 12. Jornada | 16.10.2005 | Metalurh Donetsk | - | Tavriya Simferopol (1958-2014) | 0:0 | ||||
| 13. Jornada | 23.10.2005 | Shakhtar Donetsk | - | Metalurh Donetsk | 2:0 | ||||
| 14. Jornada | 30.10.2005 | Metalurh Donetsk | - | Metalurg Zaporizhya | 0:0 | ||||
| 15. Jornada | 06.11.2005 | Arsenal Kiev | - | Metalurh Donetsk | 0:2 | ||||
| 16. Jornada | 20.11.2005 | Stal Alchevsk | - | Metalurh Donetsk | 1:1 | ||||
| 19. Jornada | 08.12.2005 | Metalurh Donetsk | - | Vorskla Poltava | 2:0 | ||||
| 23. Jornada | 25.03.2006 | Volyn Lutsk | - | Metalurh Donetsk | 1:2 |  |
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| 24. Jornada | 02.04.2006 | Metalurh Donetsk | - | Dnipro Dnipropetrovsk | 1:1 | ||||
| 25. Jornada | 08.04.2006 | FK Kharkiv | - | Metalurh Donetsk | 1:0 | ||||
| 26. Jornada | 16.04.2006 | Metalurh Donetsk | - | FK Krivbas (old) | 3:2 | ||||
| 27. Jornada | 22.04.2006 | Tavriya Simferopol (1958-2014) | - | Metalurh Donetsk | 3:0 | ||||
| 28. Jornada | 30.04.2006 | Metalurh Donetsk | - | Shakhtar Donetsk | 1:3 |
Serbia