| 6. Jornada | 19.08.2012 | Volyn Lutsk | - | Zorya Lugansk | 2:2 |  |
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| 7. Jornada | 26.08.2012 | Dnipro Dnipropetrovsk | - | Volyn Lutsk | 2:1 | ||||
| 8. Jornada | 02.09.2012 | Volyn Lutsk | - | Metalist Kharkiv | 2:1 | |
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| 9. Jornada | 15.09.2012 | FK Illichivets | - | Volyn Lutsk | 0:0 | |
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| 10. Jornada | 29.09.2012 | Volyn Lutsk | - | Tavriya Simferopol (1958-2014) | 0:1 | ||||
| 11. Jornada | 06.10.2012 | Metalurg Zaporizhya | - | Volyn Lutsk | 0:3 |  |
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| 12. Jornada | 20.10.2012 | Volyn Lutsk | - | Metalurh Donetsk | 1:1 | ||||
| 13. Jornada | 26.10.2012 | Arsenal Kiev | - | Volyn Lutsk | 1:1 | ||||
| 14. Jornada | 04.11.2012 | Volyn Lutsk | - | Hoverla Uzhgorod | 2:1 | |
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| 15. Jornada | 10.11.2012 | FK Krivbas (old) | - | Volyn Lutsk | 1:0 | |
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| 17. Jornada | 24.11.2012 | Vorskla Poltava | - | Volyn Lutsk | 0:1 | |
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| 18. Jornada | 02.12.2012 | Volyn Lutsk | - | Chernomorets Odessa | 0:2 | |
Ucrania