| 2. Jornada | 21.07.2012 | Tavriya Simferopol (1958-2014) | - | Metalist Kharkiv | 0:1 | ||||
| 6. Jornada | 18.08.2012 | Hoverla Uzhgorod | - | Metalist Kharkiv | 0:3 | ||||
| 8. Jornada | 02.09.2012 | Volyn Lutsk | - | Metalist Kharkiv | 2:1 |  |
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| 11. Jornada | 07.10.2012 | Metalist Kharkiv | - | Shakhtar Donetsk | 0:2 | |
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| 12. Jornada | 20.10.2012 | Dinamo Kiev | - | Metalist Kharkiv | 1:3 | ||||
| 15. Jornada | 11.11.2012 | Metalist Kharkiv | - | Karpaty Lviv | 2:1 | ||||
| 16. Jornada | 18.11.2012 | FK Illichivets | - | Metalist Kharkiv | 0:2 | ||||
| 17. Jornada | 26.11.2012 | Metalist Kharkiv | - | Tavriya Simferopol (1958-2014) | 5:0 | ||||
| 18. Jornada | 01.12.2012 | Metalurg Zaporizhya | - | Metalist Kharkiv | 1:3 |
Ucrania