| Grupo I | 22.10.2020 | Villarreal | - | Sivasspor | 5:3 |  |
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| Grupo I | 29.10.2020 | Qarabağ FK | - | Villarreal | 1:3 | |
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| Dieciseisavos de final | 18.02.2021 | RB Salzburg | - | Villarreal | 0:2 | |
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| Dieciseisavos de final | 25.02.2021 | Villarreal | - | RB Salzburg | 2:1 | ||||
| Octavos de final | 11.03.2021 | Dinamo Kiev | - | Villarreal | 0:2 | ||||
| Cuartos de final | 08.04.2021 | Dinamo Zagreb | - | Villarreal | 0:1 | ||||
| Cuartos de final | 15.04.2021 | Villarreal | - | Dinamo Zagreb | 2:1 | |
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| Semifinales | 29.04.2021 | Villarreal | - | Arsenal | 2:1 | ||||
| Semifinales | 06.05.2021 | Arsenal | - | Villarreal | 0:0 | ||||
| Final | 26.05.2021 | Villarreal | - | Manchester United | 11:10 pn. |
España
