| 5. Jornada | 10.09.2005 | Sporting Charleroi | - | KSV Roeselare | 1:1 | ||||
| 6. Jornada | 17.09.2005 | Lierse SK (old) | - | Sporting Charleroi | 0:0 | ||||
| 7. Jornada | 20.09.2005 | Sporting Charleroi | - | Sint-Truidense VV | 0:1 | ||||
| 8. Jornada | 24.09.2005 | KSK Beveren | - | Sporting Charleroi | 1:1 | ||||
| 9. Jornada | 30.09.2005 | Sporting Charleroi | - | Club Brugge KV | 3:3 | ||||
| 10. Jornada | 15.10.2005 | Sporting Lokeren | - | Sporting Charleroi | 4:2 | ||||
| 11. Jornada | 21.10.2005 | Standard Liège | - | Sporting Charleroi | 1:0 |  |
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| 12. Jornada | 29.10.2005 | Sporting Charleroi | - | KVC Westerlo | 2:1 | |
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| 13. Jornada | 05.11.2005 | RSC Anderlecht | - | Sporting Charleroi | 3:1 | ||||
| 17. Jornada | 10.12.2005 | Cercle Brugge | - | Sporting Charleroi | 2:0 | ||||
| 15. Jornada | 14.12.2005 | SV Zulte Waregem | - | Sporting Charleroi | 3:0 |
Francia