| 1. Jornada | 21.08.1999 | Athletic | - | Betis | 1:0 | ||||
| 2. Jornada | 29.08.1999 | Valladolid | - | Athletic | 1:0 | ||||
| 4. Jornada | 19.09.1999 | Numancia | - | Athletic | 1:1 | ||||
| 7. Jornada | 12.10.1999 | Málaga | - | Athletic | 3:4 |  |
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| 12. Jornada | 20.11.1999 | Athletic | - | Atlético | 4:2 | ||||
| 25. Jornada | 19.02.2000 | Deportivo | - | Athletic | 2:0 | ||||
| 27. Jornada | 04.03.2000 | Valencia | - | Athletic | 2:0 | ||||
| 28. Jornada | 11.03.2000 | Athletic | - | Barcelona | 0:4 | ||||
| 29. Jornada | 19.03.2000 | Real Oviedo | - | Athletic | 1:0 | ||||
| 30. Jornada | 25.03.2000 | Athletic | - | Sevilla | 1:1 | ||||
| 36. Jornada | 07.05.2000 | Athletic | - | Real Racing | 2:2 | |
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| 37. Jornada | 14.05.2000 | Espanyol | - | Athletic | 0:0 | ||||
| 38. Jornada | 19.05.2000 | Athletic | - | Alavés | 2:1 |
España