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| 21.09.1963 | Barcelona | - | Pontevedra CF | 3:1 (2:0) | ||
| 22.09.1963 | Levante | - | Betis | 0:1 (0:0) | ||
| Athletic | - | Córdoba | 2:0 (1:0) | |||
| Atlético | - | Valladolid | 3:1 (0:1) | |||
| Real Oviedo | - | Espanyol | 2:1 (1:1) | |||
| Elche | - | Real Madrid | 2:0 (0:0) | |||
| Sevilla | - | Valencia | 3:0 (0:0) | |||
| Zaragoza | - | Real Murcia | 3:2 (3:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 2 | 2 | 0 | 0 | 5:1 | 4 | 4:0 |
| 2 |
|
Betis | 2 | 2 | 0 | 0 | 4:1 | 3 | 4:0 |
| 3 |
|
Elche | 2 | 1 | 1 | 0 | 4:2 | 2 | 3:1 |
| 4 |
|
Zaragoza | 2 | 1 | 1 | 0 | 4:3 | 1 | 3:1 |
| 5 |
|
Atlético | 2 | 1 | 0 | 1 | 4:3 | 1 | 2:2 |
|
Sevilla | 2 | 1 | 0 | 1 | 4:3 | 1 | 2:2 | |
| 7 |
|
Real Murcia | 2 | 1 | 0 | 1 | 4:4 | 0 | 2:2 |
| 8 |
|
Athletic | 2 | 1 | 0 | 1 | 3:3 | 0 | 2:2 |
|
Real Madrid | 2 | 1 | 0 | 1 | 3:3 | 0 | 2:2 | |
|
Real Oviedo | 2 | 1 | 0 | 1 | 3:3 | 0 | 2:2 | |
| 11 |
|
Córdoba | 2 | 1 | 0 | 1 | 2:3 | -1 | 2:2 |
| 12 |
|
Espanyol | 2 | 0 | 1 | 1 | 5:6 | -1 | 1:3 |
| 13 |
|
Levante | 2 | 0 | 1 | 1 | 4:5 | -1 | 1:3 |
| 14 |
|
Valladolid | 2 | 0 | 1 | 1 | 3:5 | -2 | 1:3 |
| 15 |
|
Pontevedra CF | 2 | 0 | 1 | 1 | 2:4 | -2 | 1:3 |
| 16 |
|
Valencia | 2 | 0 | 0 | 2 | 0:5 | -5 | 0:4 |
