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| 29.10.1966 | Barcelona | - | Granada | 3:0 (0:0) | ||
| 30.10.1966 | Hércules CF | - | Sevilla | 2:1 (0:0) | ||
| Valencia | - | Pontevedra CF | 3:0 (2:0) | |||
| Atlético | - | CE Sabadell | 3:0 (1:0) | |||
| Athletic | - | Zaragoza | 2:3 (2:3) | |||
| Deportivo | - | Espanyol | 1:1 (0:0) | |||
| Las Palmas | - | Real Madrid | 1:1 (0:1) | |||
| Córdoba | - | Elche | 0:0 (0:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia | 7 | 5 | 2 | 0 | 16:4 | 12 | 12:2 |
| 2 |
|
Real Madrid | 7 | 4 | 3 | 0 | 12:5 | 7 | 11:3 |
| 3 |
|
Espanyol | 7 | 4 | 2 | 1 | 14:7 | 7 | 10:4 |
| 4 |
|
Zaragoza | 7 | 5 | 0 | 2 | 15:14 | 1 | 10:4 |
| 5 |
|
Barcelona | 7 | 4 | 0 | 3 | 13:8 | 5 | 8:6 |
| 6 |
|
Atlético | 7 | 3 | 1 | 3 | 7:5 | 2 | 7:7 |
| 7 |
|
Elche | 7 | 2 | 3 | 2 | 11:10 | 1 | 7:7 |
| 8 |
|
CE Sabadell | 7 | 3 | 1 | 3 | 8:11 | -3 | 7:7 |
| 9 |
|
Hércules CF | 7 | 3 | 1 | 3 | 6:12 | -6 | 7:7 |
| 10 |
|
Athletic | 7 | 2 | 2 | 3 | 8:10 | -2 | 6:8 |
| 11 |
|
Pontevedra CF | 7 | 2 | 2 | 3 | 3:6 | -3 | 6:8 |
| 12 |
|
Sevilla | 7 | 2 | 1 | 4 | 8:9 | -1 | 5:9 |
| 13 |
|
Granada | 7 | 1 | 3 | 3 | 11:13 | -2 | 5:9 |
| 14 |
|
Córdoba | 7 | 2 | 1 | 4 | 5:12 | -7 | 5:9 |
| 15 |
|
Las Palmas | 7 | 1 | 2 | 4 | 8:12 | -4 | 4:10 |
| 16 |
|
Deportivo | 7 | 0 | 2 | 5 | 2:9 | -7 | 2:12 |
