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| 19.01.1991 | Mallorca | - | Real Sociedad | 2:1 (1:0) | ||
| Barcelona | - | Real Madrid | 2:1 (1:1) | |||
| 20.01.1991 | Tenerife | - | Real Burgos | 1:0 (0:0) | ||
| Zaragoza | - | Cádiz CF | 3:0 (0:0) | |||
| Athletic | - | Valladolid | 0:1 (0:0) | |||
| CD Castellón | - | Real Oviedo | 1:0 (0:0) | |||
| Osasuna | - | Betis | 3:0 (1:0) | |||
| Atlético | - | Espanyol | 4:0 (2:0) | |||
| Sevilla | - | CD Logroñés | 1:0 (1:0) | |||
| Sporting | - | Valencia | 1:1 (1:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 19 | 14 | 3 | 2 | 35:13 | 22 | 31:7 |
| 2 |
|
Atlético | 19 | 10 | 7 | 2 | 29:10 | 19 | 27:11 |
| 3 |
|
Osasuna | 19 | 9 | 7 | 3 | 25:14 | 11 | 25:13 |
| 4 |
|
Sevilla | 19 | 10 | 3 | 6 | 22:14 | 8 | 23:15 |
| 5 |
|
CD Logroñés | 19 | 9 | 4 | 6 | 16:13 | 3 | 22:16 |
| 6 |
|
Real Madrid | 19 | 9 | 3 | 7 | 24:20 | 4 | 21:17 |
| 7 |
|
Real Oviedo | 19 | 6 | 8 | 5 | 14:20 | -6 | 20:18 |
| 8 |
|
Valencia | 19 | 7 | 5 | 7 | 23:22 | 1 | 19:19 |
| 9 |
|
Athletic | 19 | 8 | 3 | 8 | 18:22 | -4 | 19:19 |
| 10 |
|
Valladolid | 19 | 5 | 8 | 6 | 20:18 | 2 | 18:20 |
| 11 |
|
Sporting | 19 | 6 | 6 | 7 | 22:21 | 1 | 18:20 |
|
Zaragoza | 19 | 7 | 4 | 8 | 22:21 | 1 | 18:20 | |
| 13 |
|
CD Castellón | 19 | 4 | 10 | 5 | 14:16 | -2 | 18:20 |
| 14 |
|
Real Burgos | 19 | 5 | 7 | 7 | 14:12 | 2 | 17:21 |
| 15 |
|
Mallorca | 19 | 6 | 5 | 8 | 18:23 | -5 | 17:21 |
| 16 |
|
Espanyol | 19 | 5 | 5 | 9 | 17:21 | -4 | 15:23 |
| 17 |
|
Real Sociedad | 19 | 4 | 7 | 8 | 15:24 | -9 | 15:23 |
| 18 |
|
Tenerife | 19 | 6 | 3 | 10 | 18:34 | -16 | 15:23 |
| 19 |
|
Betis | 19 | 3 | 6 | 10 | 17:32 | -15 | 12:26 |
| 20 |
|
Cádiz CF | 19 | 2 | 6 | 11 | 12:25 | -13 | 10:28 |
