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| 06.04.1991 | Sporting | - | Sevilla | 2:0 (1:0) | ||
| Real Burgos | - | Barcelona | 1:3 (1:3) | |||
| 07.04.1991 | Valencia | - | Real Oviedo | 1:1 (1:0) | ||
| Betis | - | CD Logroñés | 3:2 (3:1) | |||
| Tenerife | - | Cádiz CF | 1:0 (0:0) | |||
| Osasuna | - | Mallorca | 1:0 (1:0) | |||
| Athletic | - | Zaragoza | 2:0 (1:0) | |||
| Valladolid | - | Real Sociedad | 4:2 (1:0) | |||
| Espanyol | - | Real Madrid | 3:1 (1:0) | |||
| Atlético | - | CD Castellón | 3:1 (1:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 29 | 21 | 5 | 3 | 64:23 | 41 | 47:11 |
| 2 |
|
Atlético | 29 | 16 | 11 | 2 | 46:14 | 32 | 43:15 |
| 3 |
|
Osasuna | 29 | 13 | 9 | 7 | 35:26 | 9 | 35:23 |
| 4 |
|
CD Logroñés | 29 | 12 | 8 | 9 | 22:21 | 1 | 32:26 |
| 5 |
|
Sporting | 29 | 11 | 9 | 9 | 38:31 | 7 | 31:27 |
| 6 |
|
Sevilla | 29 | 13 | 5 | 11 | 35:35 | 0 | 31:27 |
| 7 |
|
Real Oviedo | 29 | 9 | 13 | 7 | 25:31 | -6 | 31:27 |
| 8 |
|
Valencia | 29 | 11 | 8 | 10 | 33:30 | 3 | 30:28 |
| 9 |
|
Real Madrid | 29 | 12 | 5 | 12 | 41:31 | 10 | 29:29 |
| 10 |
|
Real Sociedad | 29 | 9 | 11 | 9 | 29:33 | -4 | 29:29 |
| 11 |
|
Real Burgos | 29 | 7 | 13 | 9 | 23:23 | 0 | 27:31 |
| 12 |
|
Tenerife | 29 | 11 | 5 | 13 | 28:43 | -15 | 27:31 |
| 13 |
|
Espanyol | 29 | 9 | 8 | 12 | 31:35 | -4 | 26:32 |
| 14 |
|
Valladolid | 29 | 7 | 12 | 10 | 30:34 | -4 | 26:32 |
| 15 |
|
Athletic | 29 | 11 | 4 | 14 | 26:37 | -11 | 26:32 |
| 16 |
|
Zaragoza | 29 | 8 | 8 | 13 | 27:32 | -5 | 24:34 |
| 17 |
|
CD Castellón | 29 | 7 | 10 | 12 | 24:33 | -9 | 24:34 |
| 18 |
|
Mallorca | 29 | 7 | 9 | 13 | 24:34 | -10 | 23:35 |
| 19 |
|
Betis | 29 | 6 | 8 | 15 | 30:50 | -20 | 20:38 |
| 20 |
|
Cádiz CF | 29 | 4 | 11 | 14 | 17:32 | -15 | 19:39 |
