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| 13.04.1991 | Sevilla | - | Atlético | 1:1 (0:0) | ||
| 14.04.1991 | Real Madrid | - | Valencia | 4:0 (1:0) | ||
| Espanyol | - | Real Burgos | 1:0 (1:0) | |||
| Zaragoza | - | Osasuna | 0:0 (0:0) | |||
| CD Logroñés | - | Valladolid | 1:2 (0:1) | |||
| Real Oviedo | - | Betis | 1:0 (1:0) | |||
| Real Sociedad | - | Tenerife | 1:3 (1:1) | |||
| Cádiz CF | - | Athletic | 2:3 (0:1) | |||
| CD Castellón | - | Barcelona | 0:1 (0:0) | |||
| Mallorca | - | Sporting | 1:1 (1:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 30 | 22 | 5 | 3 | 65:23 | 42 | 49:11 |
| 2 |
|
Atlético | 30 | 16 | 12 | 2 | 47:15 | 32 | 44:16 |
| 3 |
|
Osasuna | 30 | 13 | 10 | 7 | 35:26 | 9 | 36:24 |
| 4 |
|
Real Oviedo | 30 | 10 | 13 | 7 | 26:31 | -5 | 33:27 |
| 5 |
|
Sporting | 30 | 11 | 10 | 9 | 39:32 | 7 | 32:28 |
| 6 |
|
Sevilla | 30 | 13 | 6 | 11 | 36:36 | 0 | 32:28 |
| 7 |
|
CD Logroñés | 30 | 12 | 8 | 10 | 23:23 | 0 | 32:28 |
| 8 |
|
Real Madrid | 30 | 13 | 5 | 12 | 45:31 | 14 | 31:29 |
| 9 |
|
Valencia | 30 | 11 | 8 | 11 | 33:34 | -1 | 30:30 |
| 10 |
|
Real Sociedad | 30 | 9 | 11 | 10 | 30:36 | -6 | 29:31 |
| 11 |
|
Tenerife | 30 | 12 | 5 | 13 | 31:44 | -13 | 29:31 |
| 12 |
|
Espanyol | 30 | 10 | 8 | 12 | 32:35 | -3 | 28:32 |
|
Valladolid | 30 | 8 | 12 | 10 | 32:35 | -3 | 28:32 | |
| 14 |
|
Athletic | 30 | 12 | 4 | 14 | 29:39 | -10 | 28:32 |
| 15 |
|
Real Burgos | 30 | 7 | 13 | 10 | 23:24 | -1 | 27:33 |
| 16 |
|
Zaragoza | 30 | 8 | 9 | 13 | 27:32 | -5 | 25:35 |
| 17 |
|
Mallorca | 30 | 7 | 10 | 13 | 25:35 | -10 | 24:36 |
| 18 |
|
CD Castellón | 30 | 7 | 10 | 13 | 24:34 | -10 | 24:36 |
| 19 |
|
Betis | 30 | 6 | 8 | 16 | 30:51 | -21 | 20:40 |
| 20 |
|
Cádiz CF | 30 | 4 | 11 | 15 | 19:35 | -16 | 19:41 |
