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| 11.03.2006 | 18:00 | Espanyol | - | Celta | 2:0 (2:0) | |
| 20:00 | Deportivo | - | Real Sociedad | 0:1 (0:0) | ||
| 22:00 | Valencia | - | Real Madrid | 0:0 (0:0) | ||
| 12.03.2006 | 17:00 | Mallorca | - | Villarreal | 1:1 (1:1) | |
| 17:00 | Alavés | - | Sevilla | 2:1 (2:1) | ||
| 17:00 | Athletic | - | Cádiz CF | 1:0 (0:0) | ||
| 17:00 | Zaragoza | - | Getafe | 1:2 (1:1) | ||
| 17:00 | Betis | - | Málaga | 1:1 (1:0) | ||
| 19:00 | Atlético | - | Real Racing | 2:1 (0:0) | ||
| 21:00 | Osasuna | - | Barcelona | 2:1 (1:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 27 | 19 | 4 | 4 | 64:25 | 39 | 61 |
| 2 |
|
Real Madrid | 27 | 16 | 4 | 7 | 50:26 | 24 | 52 |
| 3 |
|
Valencia | 27 | 14 | 10 | 3 | 37:21 | 16 | 52 |
| 4 |
|
Osasuna | 27 | 15 | 4 | 8 | 35:30 | 5 | 49 |
| 5 |
|
Celta | 27 | 14 | 3 | 10 | 29:27 | 2 | 45 |
| 6 |
|
Sevilla | 27 | 13 | 5 | 9 | 35:29 | 6 | 44 |
| 7 |
|
Villarreal | 27 | 11 | 10 | 6 | 37:26 | 11 | 43 |
| 8 |
|
Atlético | 27 | 11 | 8 | 8 | 38:26 | 12 | 41 |
| 9 |
|
Deportivo | 27 | 11 | 7 | 9 | 36:31 | 5 | 40 |
| 10 |
|
Getafe | 27 | 10 | 7 | 10 | 36:34 | 2 | 37 |
| 11 |
|
Zaragoza | 27 | 8 | 12 | 7 | 37:37 | 0 | 36 |
| 12 |
|
Espanyol | 27 | 8 | 6 | 13 | 27:41 | -14 | 30 |
| 13 |
|
Real Racing | 27 | 6 | 11 | 10 | 24:31 | -7 | 29 |
| 14 |
|
Real Sociedad | 27 | 8 | 4 | 15 | 35:51 | -16 | 28 |
| 15 |
|
Mallorca | 27 | 6 | 9 | 12 | 27:42 | -15 | 27 |
| 16 |
|
Athletic | 27 | 6 | 8 | 13 | 29:37 | -8 | 26 |
| 17 |
|
Alavés | 27 | 6 | 8 | 13 | 30:45 | -15 | 26 |
| 18 |
|
Betis | 27 | 6 | 8 | 13 | 24:39 | -15 | 26 |
| 19 |
|
Cádiz CF | 27 | 6 | 7 | 14 | 20:36 | -16 | 25 |
| 20 |
|
Málaga | 27 | 5 | 7 | 15 | 29:45 | -16 | 22 |
