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| 03.05.2006 | 20:00 | Mallorca | - | Valencia | 2:1 (1:1) | |
| 20:00 | Alavés | - | Betis | 2:0 (1:0) | ||
| 20:00 | Athletic | - | Zaragoza | 1:0 (0:0) | ||
| 20:00 | Espanyol | - | Deportivo | 1:2 (1:0) | ||
| 20:00 | Cádiz CF | - | Real Sociedad | 2:2 (0:1) | ||
| 20:00 | Sevilla | - | Getafe | 3:0 (3:0) | ||
| 20:00 | Villarreal | - | Málaga | 2:1 (2:1) | ||
| 20:00 | Atlético | - | Osasuna | 0:1 (0:1) | ||
| 21:00 | Celta | - | Barcelona | 0:1 (0:0) | ||
| 04.05.2006 | 22:00 | Real Racing | - | Real Madrid | 2:3 (0:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 36 | 24 | 7 | 5 | 77:32 | 45 | 79 |
| 2 |
|
Real Madrid | 36 | 20 | 9 | 7 | 64:33 | 31 | 69 |
| 3 |
|
Valencia | 36 | 19 | 11 | 6 | 56:30 | 26 | 68 |
| 4 |
|
Osasuna | 36 | 20 | 5 | 11 | 46:40 | 6 | 65 |
| 5 |
|
Sevilla | 36 | 18 | 8 | 10 | 48:36 | 12 | 62 |
| 6 |
|
Celta | 36 | 19 | 3 | 14 | 42:31 | 11 | 60 |
| 7 |
|
Deportivo | 36 | 15 | 10 | 11 | 46:42 | 4 | 55 |
| 8 |
|
Villarreal | 36 | 13 | 14 | 9 | 45:36 | 9 | 53 |
| 9 |
|
Getafe | 36 | 14 | 9 | 13 | 51:47 | 4 | 51 |
| 10 |
|
Atlético | 36 | 13 | 11 | 12 | 43:35 | 8 | 50 |
| 11 |
|
Zaragoza | 36 | 9 | 16 | 11 | 42:48 | -6 | 43 |
| 12 |
|
Mallorca | 36 | 9 | 13 | 14 | 33:48 | -15 | 40 |
| 13 |
|
Athletic | 36 | 9 | 12 | 15 | 35:44 | -9 | 39 |
| 14 |
|
Real Sociedad | 36 | 11 | 6 | 19 | 46:62 | -16 | 39 |
| 15 |
|
Betis | 36 | 9 | 11 | 16 | 31:49 | -18 | 38 |
| 16 |
|
Espanyol | 36 | 9 | 11 | 16 | 35:54 | -19 | 38 |
| 17 |
|
Real Racing | 36 | 8 | 13 | 15 | 34:46 | -12 | 37 |
| 18 |
|
Alavés | 36 | 8 | 12 | 16 | 34:51 | -17 | 36 |
| 19 |
|
Cádiz CF | 36 | 7 | 12 | 17 | 30:49 | -19 | 33 |
| 20 |
|
Málaga | 36 | 5 | 9 | 22 | 36:61 | -25 | 24 |
