| 1. Jornada | 02.09.1990 | Tenerife | - | Athletic | 1:0 | ||||
| 2. Jornada | 09.09.1990 | Athletic | - | Real Burgos | 2:1 | ||||
| 3. Jornada | 16.09.1990 | Athletic | - | Osasuna | 2:0 | ||||
| 4. Jornada | 23.09.1990 | Sporting | - | Athletic | 3:1 | ||||
| 5. Jornada | 29.09.1990 | Athletic | - | Atlético | 2:1 | ||||
| 6. Jornada | 06.10.1990 | Barcelona | - | Athletic | 4:1 | ||||
| 7. Jornada | 14.10.1990 | Athletic | - | CD Castellón | 1:1 | ||||
| 8. Jornada | 20.10.1990 | Sevilla | - | Athletic | 3:0 | ||||
| 9. Jornada | 28.10.1990 | Athletic | - | Mallorca | 2:0 | ||||
| 10. Jornada | 04.11.1990 | Zaragoza | - | Athletic | 1:0 |  |
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| 11. Jornada | 18.11.1990 | Athletic | - | Cádiz CF | 1:0 | ||||
| 18. Jornada | 13.01.1991 | Betis | - | Athletic | 1:0 | ||||
| 20. Jornada | 27.01.1991 | Athletic | - | Tenerife | 2:0 | ||||
| 26. Jornada | 16.03.1991 | CD Castellón | - | Athletic | 2:0 | ||||
| 29. Jornada | 07.04.1991 | Athletic | - | Zaragoza | 2:0 | ||||
| 30. Jornada | 14.04.1991 | Cádiz CF | - | Athletic | 2:3 | ||||
| 35. Jornada | 19.05.1991 | Athletic | - | Espanyol | 1:1 | ||||
| 36. Jornada | 25.05.1991 | Valencia | - | Athletic | 2:1 | |
España