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| 16.03.1991 | Barcelona | - | Osasuna | 2:0 (2:0) | ||
| CD Castellón | - | Athletic | 2:0 (0:0) | |||
| CD Logroñés | - | Real Madrid | 1:0 (1:0) | |||
| 17.03.1991 | Zaragoza | - | Betis | 2:0 (2:0) | ||
| Real Oviedo | - | Real Burgos | 1:1 (0:1) | |||
| Sevilla | - | Tenerife | 2:2 (2:1) | |||
| Mallorca | - | Valladolid | 0:0 (0:0) | |||
| Atlético | - | Sporting | 3:1 (2:1) | |||
| Real Sociedad | - | Espanyol | 0:0 (0:0) | |||
| Cádiz CF | - | Valencia | 0:0 (0:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 26 | 20 | 4 | 2 | 60:20 | 40 | 44:8 |
| 2 |
|
Atlético | 26 | 15 | 9 | 2 | 41:11 | 30 | 39:13 |
| 3 |
|
Osasuna | 26 | 11 | 9 | 6 | 31:24 | 7 | 31:21 |
| 4 |
|
Valencia | 26 | 11 | 7 | 8 | 32:27 | 5 | 29:23 |
| 5 |
|
Sevilla | 26 | 12 | 5 | 9 | 33:30 | 3 | 29:23 |
| 6 |
|
Real Madrid | 26 | 12 | 4 | 10 | 39:26 | 13 | 28:24 |
| 7 |
|
CD Logroñés | 26 | 10 | 8 | 8 | 18:18 | 0 | 28:24 |
| 8 |
|
Sporting | 26 | 9 | 9 | 8 | 33:28 | 5 | 27:25 |
| 9 |
|
Real Oviedo | 26 | 8 | 11 | 7 | 19:28 | -9 | 27:25 |
| 10 |
|
Real Sociedad | 26 | 7 | 11 | 8 | 25:29 | -4 | 25:27 |
| 11 |
|
Real Burgos | 26 | 6 | 12 | 8 | 20:19 | 1 | 24:28 |
| 12 |
|
Espanyol | 26 | 8 | 8 | 10 | 27:29 | -2 | 24:28 |
| 13 |
|
Zaragoza | 26 | 8 | 7 | 11 | 27:29 | -2 | 23:29 |
| 14 |
|
Valladolid | 26 | 6 | 10 | 10 | 26:32 | -6 | 22:30 |
| 15 |
|
CD Castellón | 26 | 6 | 10 | 10 | 20:26 | -6 | 22:30 |
| 16 |
|
Mallorca | 26 | 7 | 8 | 11 | 23:31 | -8 | 22:30 |
| 17 |
|
Athletic | 26 | 9 | 3 | 14 | 22:37 | -15 | 21:31 |
| 18 |
|
Tenerife | 26 | 8 | 5 | 13 | 24:42 | -18 | 21:31 |
| 19 |
|
Cádiz CF | 26 | 4 | 10 | 12 | 17:28 | -11 | 18:34 |
| 20 |
|
Betis | 26 | 4 | 8 | 14 | 24:47 | -23 | 16:36 |
