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| 09.02.1991 | Osasuna | - | Athletic | 1:0 (1:0) | ||
| 10.02.1991 | Atlético | - | Valladolid | 2:0 (0:0) | ||
| Mallorca | - | Real Madrid | 1:1 (1:0) | |||
| Sporting | - | Tenerife | 2:1 (2:0) | |||
| Cádiz CF | - | CD Logroñés | 2:0 (0:0) | |||
| Real Sociedad | - | Real Burgos | 3:1 (0:1) | |||
| Barcelona | - | Betis | 4:2 (2:0) | |||
| Sevilla | - | Espanyol | 1:1 (0:1) | |||
| Zaragoza | - | Real Oviedo | 0:1 (0:1) | |||
| CD Castellón | - | Valencia | 0:2 (0:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 22 | 16 | 4 | 2 | 46:19 | 27 | 36:8 |
| 2 |
|
Atlético | 22 | 12 | 8 | 2 | 33:10 | 23 | 32:12 |
| 3 |
|
Osasuna | 22 | 11 | 7 | 4 | 29:17 | 12 | 29:15 |
| 4 |
|
Real Madrid | 22 | 11 | 4 | 7 | 35:21 | 14 | 26:18 |
| 5 |
|
Sevilla | 22 | 11 | 4 | 7 | 26:22 | 4 | 26:18 |
| 6 |
|
Real Oviedo | 22 | 8 | 8 | 6 | 16:23 | -7 | 24:20 |
| 7 |
|
Sporting | 22 | 8 | 7 | 7 | 28:22 | 6 | 23:21 |
| 8 |
|
CD Logroñés | 22 | 9 | 5 | 8 | 17:18 | -1 | 23:21 |
| 9 |
|
Valencia | 22 | 8 | 6 | 8 | 27:26 | 1 | 22:22 |
| 10 |
|
Athletic | 22 | 9 | 3 | 10 | 21:25 | -4 | 21:23 |
| 11 |
|
Real Burgos | 22 | 6 | 8 | 8 | 17:16 | 1 | 20:24 |
| 12 |
|
Zaragoza | 22 | 7 | 6 | 9 | 24:24 | 0 | 20:24 |
| 13 |
|
Mallorca | 22 | 7 | 6 | 9 | 21:25 | -4 | 20:24 |
| 14 |
|
Valladolid | 22 | 5 | 9 | 8 | 21:22 | -1 | 19:25 |
| 15 |
|
Real Sociedad | 22 | 5 | 9 | 8 | 19:26 | -7 | 19:25 |
| 16 |
|
Espanyol | 22 | 6 | 6 | 10 | 21:27 | -6 | 18:26 |
| 17 |
|
CD Castellón | 22 | 4 | 10 | 8 | 14:22 | -8 | 18:26 |
| 18 |
|
Tenerife | 22 | 7 | 3 | 12 | 21:39 | -18 | 17:27 |
| 19 |
|
Cádiz CF | 22 | 3 | 8 | 11 | 14:25 | -11 | 14:30 |
| 20 |
|
Betis | 22 | 3 | 7 | 12 | 19:40 | -21 | 13:31 |
