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| 30.10.1999 | Deportivo | - | Barcelona | 2:1 (2:0) | ||
| Real Madrid | - | Atlético | 1:3 (1:3) | |||
| Málaga | - | Valencia | 1:1 (1:0) | |||
| 31.10.1999 | Espanyol | - | Zaragoza | 1:1 (0:1) | ||
| Numancia | - | Sevilla | 2:0 (1:0) | |||
| Valladolid | - | Rayo | 1:2 (0:1) | |||
| Alavés | - | Celta | 1:0 (0:0) | |||
| Real Racing | - | Mallorca | 1:1 (0:0) | |||
| Athletic | - | Real Oviedo | 1:1 (1:1) | |||
| Betis | - | Real Sociedad | 1:0 (1:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Rayo | 10 | 7 | 1 | 2 | 14:9 | 5 | 22 |
| 2 |
|
Barcelona | 10 | 6 | 2 | 2 | 24:11 | 13 | 20 |
| 3 |
|
Zaragoza | 10 | 5 | 3 | 2 | 17:7 | 10 | 18 |
| 4 |
|
Deportivo | 10 | 5 | 3 | 2 | 18:12 | 6 | 18 |
| 5 |
|
Celta | 10 | 6 | 0 | 4 | 11:10 | 1 | 18 |
| 6 |
|
Betis | 10 | 5 | 1 | 4 | 9:13 | -4 | 16 |
| 7 |
|
Real Racing | 10 | 4 | 3 | 3 | 18:16 | 2 | 15 |
| 8 |
|
Espanyol | 10 | 4 | 2 | 4 | 13:14 | -1 | 14 |
| 9 |
|
Alavés | 10 | 4 | 2 | 4 | 9:10 | -1 | 14 |
| 10 |
|
Atlético | 10 | 4 | 1 | 5 | 14:16 | -2 | 13 |
| 11 |
|
Real Madrid | 10 | 2 | 6 | 2 | 18:17 | 1 | 12 |
| 12 |
|
Athletic | 10 | 3 | 3 | 4 | 13:17 | -4 | 12 |
| 13 |
|
Real Oviedo | 10 | 3 | 3 | 4 | 9:13 | -4 | 12 |
| 14 |
|
Numancia | 10 | 3 | 3 | 4 | 11:17 | -6 | 12 |
| 15 |
|
Valencia | 10 | 3 | 2 | 5 | 13:12 | 1 | 11 |
| 16 |
|
Mallorca | 10 | 3 | 2 | 5 | 13:15 | -2 | 11 |
| 17 |
|
Valladolid | 10 | 3 | 2 | 5 | 10:14 | -4 | 11 |
| 18 |
|
Málaga | 10 | 2 | 3 | 5 | 15:19 | -4 | 9 |
| 19 |
|
Real Sociedad | 10 | 2 | 3 | 5 | 12:17 | -5 | 9 |
| 20 |
|
Sevilla | 10 | 1 | 5 | 4 | 11:13 | -2 | 8 |
