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| 21.10.2000 | Barcelona | - | Real Madrid | 2:0 (1:0) | ||
| Deportivo | - | Mallorca | 1:1 (0:0) | |||
| Valencia | - | Zaragoza | 1:0 (0:0) | |||
| 22.10.2000 | Valladolid | - | Osasuna | 1:1 (1:1) | ||
| Real Racing | - | Numancia | 4:2 (2:1) | |||
| Athletic | - | Las Palmas | 0:3 (0:1) | |||
| Real Oviedo | - | Celta | 3:1 (2:0) | |||
| Alavés | - | Espanyol | 1:0 (0:0) | |||
| Rayo | - | Real Sociedad | 4:1 (2:1) | |||
| Málaga | - | Villarreal | 2:1 (2:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia | 6 | 4 | 1 | 1 | 15:4 | 11 | 13 |
| 2 |
|
Rayo | 6 | 3 | 3 | 0 | 14:4 | 10 | 12 |
| 3 |
|
Barcelona | 6 | 4 | 0 | 2 | 14:7 | 7 | 12 |
| 4 |
|
Real Madrid | 6 | 3 | 2 | 1 | 12:7 | 5 | 11 |
| 5 |
|
Alavés | 6 | 3 | 2 | 1 | 9:4 | 5 | 11 |
| 6 |
|
Deportivo | 6 | 3 | 2 | 1 | 9:5 | 4 | 11 |
| 7 |
|
Celta | 6 | 3 | 1 | 2 | 9:8 | 1 | 10 |
| 8 |
|
Valladolid | 6 | 1 | 5 | 0 | 5:3 | 2 | 8 |
| 9 |
|
Real Oviedo | 6 | 2 | 2 | 2 | 7:6 | 1 | 8 |
| 10 |
|
Las Palmas | 6 | 2 | 2 | 2 | 9:12 | -3 | 8 |
| 11 |
|
Villarreal | 6 | 2 | 2 | 2 | 5:8 | -3 | 8 |
| 12 |
|
Málaga | 6 | 2 | 1 | 3 | 9:11 | -2 | 7 |
| 13 |
|
Numancia | 6 | 2 | 1 | 3 | 6:10 | -4 | 7 |
| 14 |
|
Athletic | 6 | 2 | 1 | 3 | 6:11 | -5 | 7 |
| 15 |
|
Osasuna | 6 | 1 | 3 | 2 | 5:8 | -3 | 6 |
| 16 |
|
Real Racing | 6 | 1 | 2 | 3 | 8:12 | -4 | 5 |
| 17 |
|
Mallorca | 6 | 1 | 2 | 3 | 5:10 | -5 | 5 |
| 18 |
|
Real Sociedad | 6 | 1 | 2 | 3 | 7:18 | -11 | 5 |
| 19 |
|
Espanyol | 6 | 1 | 1 | 4 | 4:7 | -3 | 4 |
| 20 |
|
Zaragoza | 6 | 0 | 3 | 3 | 4:7 | -3 | 3 |
