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| 24.09.2008 | 20:00 | Barcelona | - | Betis | 3:2 (2:0) | |
| 20:00 | Villarreal | - | Real Racing | 2:0 (2:0) | ||
| 20:00 | Osasuna | - | Deportivo | 0:0 (0:0) | ||
| 21:00 | Getafe | - | Atlético | 1:2 (0:1) | ||
| 22:00 | Sevilla | - | Espanyol | 2:0 (0:0) | ||
| 22:00 | Real Madrid | - | Sporting | 7:1 (3:0) | ||
| 25.09.2008 | 20:00 | Málaga | - | Valencia | 0:2 (0:0) | |
| 20:00 | Valladolid | - | Almería | 2:0 (0:0) | ||
| 20:00 | RC Recreativo | - | Athletic | 1:1 (0:0) | ||
| 20:00 | Mallorca | - | Numancia | 2:0 (1:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia | 4 | 3 | 1 | 0 | 8:2 | 6 | 10 |
| 2 |
|
Villarreal | 4 | 3 | 1 | 0 | 6:2 | 4 | 10 |
| 3 |
|
Real Madrid | 4 | 3 | 0 | 1 | 14:6 | 8 | 9 |
| 4 |
|
Atlético | 4 | 3 | 0 | 1 | 11:3 | 8 | 9 |
| 5 |
|
Sevilla | 4 | 2 | 2 | 0 | 7:4 | 3 | 8 |
| 6 |
|
Barcelona | 4 | 2 | 1 | 1 | 10:5 | 5 | 7 |
| 7 |
|
Almería | 4 | 2 | 1 | 1 | 6:5 | 1 | 7 |
| 8 |
|
Espanyol | 4 | 2 | 1 | 1 | 3:3 | 0 | 7 |
| 9 |
|
Valladolid | 4 | 2 | 0 | 2 | 4:4 | 0 | 6 |
| 10 |
|
Athletic | 4 | 1 | 2 | 1 | 4:4 | 0 | 5 |
|
Getafe | 4 | 1 | 2 | 1 | 4:4 | 0 | 5 | |
| 12 |
|
Deportivo | 4 | 1 | 2 | 1 | 2:2 | 0 | 5 |
| 13 |
|
Mallorca | 4 | 1 | 2 | 1 | 3:4 | -1 | 5 |
| 14 |
|
RC Recreativo | 4 | 1 | 1 | 2 | 2:6 | -4 | 4 |
| 15 |
|
Osasuna | 4 | 0 | 3 | 1 | 2:3 | -1 | 3 |
| 16 |
|
Numancia | 4 | 1 | 0 | 3 | 5:8 | -3 | 3 |
| 17 |
|
Betis | 4 | 0 | 2 | 2 | 2:4 | -2 | 2 |
| 18 |
|
Real Racing | 4 | 0 | 2 | 2 | 2:6 | -4 | 2 |
| 19 |
|
Málaga | 4 | 0 | 1 | 3 | 0:7 | -7 | 1 |
| 20 |
|
Sporting | 4 | 0 | 0 | 4 | 6:19 | -13 | 0 |
| Champions League | |
| CL Ronda previa | |
| Europa League | |
| Descenso |
