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| 23.02.1991 | Valencia | - | Sevilla | 2:1 (2:1) | ||
| 24.02.1991 | CD Logroñés | - | Real Sociedad | 0:0 (0:0) | ||
| Real Oviedo | - | Cádiz CF | 1:1 (1:1) | |||
| Espanyol | - | Mallorca | 3:0 (2:0) | |||
| Betis | - | CD Castellón | 1:0 (0:0) | |||
| Real Burgos | - | Osasuna | 1:1 (0:0) | |||
| Real Madrid | - | Zaragoza | 2:0 (2:0) | |||
| Tenerife | - | Atlético | 0:0 (0:0) | |||
| Valladolid | - | Barcelona | 1:5 (1:2) | |||
| Athletic | - | Sporting | 1:2 (0:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 23 | 17 | 4 | 2 | 51:20 | 31 | 38:8 |
| 2 |
|
Atlético | 23 | 12 | 9 | 2 | 33:10 | 23 | 33:13 |
| 3 |
|
Osasuna | 23 | 11 | 8 | 4 | 30:18 | 12 | 30:16 |
| 4 |
|
Real Madrid | 23 | 12 | 4 | 7 | 37:21 | 16 | 28:18 |
| 5 |
|
Sevilla | 23 | 11 | 4 | 8 | 27:24 | 3 | 26:20 |
| 6 |
|
Sporting | 23 | 9 | 7 | 7 | 30:23 | 7 | 25:21 |
| 7 |
|
Real Oviedo | 23 | 8 | 9 | 6 | 17:24 | -7 | 25:21 |
| 8 |
|
Valencia | 23 | 9 | 6 | 8 | 29:27 | 2 | 24:22 |
| 9 |
|
CD Logroñés | 23 | 9 | 6 | 8 | 17:18 | -1 | 24:22 |
| 10 |
|
Real Burgos | 23 | 6 | 9 | 8 | 18:17 | 1 | 21:25 |
| 11 |
|
Athletic | 23 | 9 | 3 | 11 | 22:27 | -5 | 21:25 |
| 12 |
|
Zaragoza | 23 | 7 | 6 | 10 | 24:26 | -2 | 20:26 |
| 13 |
|
Espanyol | 23 | 7 | 6 | 10 | 24:27 | -3 | 20:26 |
| 14 |
|
Mallorca | 23 | 7 | 6 | 10 | 21:28 | -7 | 20:26 |
| 15 |
|
Real Sociedad | 23 | 5 | 10 | 8 | 19:26 | -7 | 20:26 |
| 16 |
|
Valladolid | 23 | 5 | 9 | 9 | 22:27 | -5 | 19:27 |
| 17 |
|
CD Castellón | 23 | 4 | 10 | 9 | 14:23 | -9 | 18:28 |
| 18 |
|
Tenerife | 23 | 7 | 4 | 12 | 21:39 | -18 | 18:28 |
| 19 |
|
Cádiz CF | 23 | 3 | 9 | 11 | 15:26 | -11 | 15:31 |
| 20 |
|
Betis | 23 | 4 | 7 | 12 | 20:40 | -20 | 15:31 |
