| 1. Jornada | 27.08.2011 | US Grosseto FC | - | AS Gubbio | 2:0 | ||||
| 3. Jornada | 03.09.2011 | Reggina Calcio | - | US Grosseto FC | 1:1 |  |
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| 5. Jornada | 17.09.2011 | Sampdoria | - | US Grosseto FC | 0:0 | |
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| 6. Jornada | 24.09.2011 | US Grosseto FC | - | FC Crotone | 2:0 | ||||
| 8. Jornada | 05.10.2011 | Torino | - | US Grosseto FC | 1:0 | ||||
| 9. Jornada | 09.10.2011 | US Grosseto FC | - | Vicenza Calcio | 1:1 | ||||
| 10. Jornada | 15.10.2011 | AS Cittadella | - | US Grosseto FC | 2:0 | ||||
| 11. Jornada | 22.10.2011 | US Grosseto FC | - | Brescia Calcio | 2:0 | ||||
| 12. Jornada | 29.10.2011 | Sassuolo | - | US Grosseto FC | 1:0 | |
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| 13. Jornada | 01.11.2011 | US Grosseto FC | - | AS Bari | 0:1 | |
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| 15. Jornada | 13.11.2011 | US Grosseto FC | - | AS Varese 1910 | 1:5 | ||||
| 17. Jornada | 26.11.2011 | US Grosseto FC | - | Juve Stabia | 0:3 | ||||
| 19. Jornada | 10.12.2011 | US Grosseto FC | - | Modena FC | 1:1 | ||||
| 21. Jornada | 06.01.2012 | US Grosseto FC | - | AS Livorno | 1:1 | ||||
| 23. Jornada | 21.01.2012 | US Grosseto FC | - | UC AlbinoLeffe | 1:0 |
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