| 3. Jornada | 09.09.2012 | Pro Vercelli | - | AS Livorno | 1:2 | ||||
| 4. Jornada | 15.09.2012 | AS Livorno | - | Empoli | 4:2 |  |
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| 5. Jornada | 22.09.2012 | Modena FC | - | AS Livorno | 1:0 | ||||
| 6. Jornada | 25.09.2012 | AS Livorno | - | AS Cittadella | 2:2 | ||||
| 26. Jornada | 16.02.2013 | AS Livorno | - | Modena FC | 1:2 | ||||
| 27. Jornada | 23.02.2013 | AS Cittadella | - | AS Livorno | 0:2 | ||||
| 28. Jornada | 26.02.2013 | AS Livorno | - | FC Crotone | 1:2 | ||||
| 33. Jornada | 24.03.2013 | AS Livorno | - | Virtus Lanciano | 2:0 | ||||
| 35. Jornada | 06.04.2013 | AS Livorno | - | Ascoli Calcio | 3:0 | |
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| 37. Jornada | 17.04.2013 | AS Livorno | - | Novara Calcio | 1:3 |
Italia