| 1. Jornada | 15.08.2021 | Barcelona | - | Real Sociedad | 4:2 |  |
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| 2. Jornada | 21.08.2021 | Athletic | - | Barcelona | 1:1 | ||||
| 3. Jornada | 29.08.2021 | Barcelona | - | Getafe | 2:1 | |
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| 5. Jornada | 20.09.2021 | Barcelona | - | Granada | 1:1 | ||||
| 6. Jornada | 23.09.2021 | Cádiz CF | - | Barcelona | 0:0 |  |
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| 8. Jornada | 02.10.2021 | Atlético | - | Barcelona | 2:0 | ||||
| 9. Jornada | 17.10.2021 | Barcelona | - | Valencia | 3:1 | ||||
| 10. Jornada | 24.10.2021 | Barcelona | - | Real Madrid | 1:2 | ||||
| 11. Jornada | 27.10.2021 | Rayo | - | Barcelona | 1:0 |
España
