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| I | Reggina Calcio | - | Chievo | 2:2 (2:0) | ||
| V | Chievo | - | Reggina Calcio | 1:1 (1:0) | ||
| I: 08.11.2006 13:30 | V: 30.11.2006 15:00 | Campeones: Chievo | ||||
| I | Empoli | - | Génova | 1:0 (1:0) | ||
| V | Génova | - | Empoli | 0:1 (0:1) | ||
| I: 08.11.2006 20:30 | V: 06.12.2006 20:30 | Campeones: Empoli | ||||
| I | Sampdoria | - | Palermo | 1:0 (0:0) | ||
| V | Palermo | - | Sampdoria | 2:3 (0:2) | ||
| I: 08.11.2006 20:30 | V: 30.11.2006 21:00 | Campeones: Sampdoria | ||||
| I | Milan | - | Brescia Calcio | 4:2 (0:2) | ||
| V | Brescia Calcio | - | Milan | 1:2 (1:2) | ||
| I: 08.11.2006 20:30 | V: 28.11.2006 21:00 | Campeones: Milan | ||||
| I | AC Arezzo | - | AS Livorno | 2:1 (1:0) | ||
| V | AS Livorno | - | AC Arezzo | 1:1 (1:0) | ||
| I: 08.11.2006 20:30 | V: 06.12.2006 20:45 | Campeones: AC Arezzo | ||||
| I | US Triestina | - | Roma | 1:2 (0:1) | ||
| V | Roma | - | US Triestina | 2:0 (2:0) | ||
| I: 08.11.2006 20:30 | V: 29.11.2006 17:00 | Campeones: Roma | ||||
| I | FC Messina | - | Inter | 0:1 (0:1) | ||
| V | Inter | - | FC Messina | 4:0 (2:0) | ||
| I: 09.11.2006 20:30 | V: 29.11.2006 21:00 | Campeones: Inter | ||||
| I | Nápoles | - | Parma FC | 1:0 (0:0) | ||
| V | Parma FC | - | Nápoles | 3:1 (1:0) | ||
| I: 09.11.2006 21:00 | V: 07.12.2006 15:00 | Campeones: Parma FC | ||||
