| 1. Jornada | 28.07.2012 | KV Mechelen | - | Sporting Charleroi | 4:2 |  |
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| 2. Jornada | 04.08.2012 | Sporting Charleroi | - | Club Brugge KV | 0:1 | |
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| 6. Jornada | 01.09.2012 | Sporting Charleroi | - | Gante | 1:1 | ||||
| 11. Jornada | 20.10.2012 | Lierse SK (old) | - | Sporting Charleroi | 0:1 | ||||
| 13. Jornada | 31.10.2012 | SV Zulte Waregem | - | Sporting Charleroi | 4:1 | ||||
| 14. Jornada | 03.11.2012 | Sporting Charleroi | - | Sporting Lokeren | 0:2 | ||||
| 16. Jornada | 17.11.2012 | Sporting Charleroi | - | KV Mechelen | 1:1 | ||||
| 17. Jornada | 25.11.2012 | Club Brugge KV | - | Sporting Charleroi | 1:0 | ||||
| 18. Jornada | 01.12.2012 | Sporting Charleroi | - | KV Kortrijk | 2:0 | ||||
| 19. Jornada | 07.12.2012 | Standard Liège | - | Sporting Charleroi | 6:1 | ||||
| 20. Jornada | 15.12.2012 | Sporting Charleroi | - | Beerschot AC | 1:0 | ||||
| 21. Jornada | 22.12.2012 | Gante | - | Sporting Charleroi | 1:2 |  |
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| 23. Jornada | 19.01.2013 | KRC Genk | - | Sporting Charleroi | 3:1 |
Ucrania