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| I | PFC Litex Lovech | - | RC Strasbourg | 0:2 (0:1) | ||
| V | RC Strasbourg | - | PFC Litex Lovech | 0:0 (0:0) | ||
| I: 15.02.2006 15:30 | V: 23.02.2006 19:00 | Campeones: RC Strasbourg | ||||
| I | Lokomotiv Moskva | - | Sevilla | 0:1 (0:0) | ||
| V | Sevilla | - | Lokomotiv Moskva | 2:0 (1:0) | ||
| I: 15.02.2006 17:30 | V: 23.02.2006 21:30 | Campeones: Sevilla | ||||
| I | FC Artmedia Bratislava | - | Levski Sofia | 0:1 (0:1) | ||
| V | Levski Sofia | - | FC Artmedia Bratislava | 2:0 (2:0) | ||
| I: 15.02.2006 17:30 | V: 23.02.2006 17:00 | Campeones: Levski Sofia | ||||
| I | Hertha | - | Rapid Bucureşti | 0:1 (0:0) | ||
| V | Rapid Bucureşti | - | Hertha | 2:0 (0:0) | ||
| I: 15.02.2006 18:00 | V: 23.02.2006 16:15 | Campeones: Rapid Bucureşti | ||||
| I | Basilea | - | Mónaco | 1:0 (0:0) | ||
| V | Mónaco | - | Basilea | 1:1 (1:0) | ||
| I: 15.02.2006 18:00 | V: 23.02.2006 20:45 | Campeones: Basilea | ||||
| I | Lille | - | Shakhtar Donetsk | 3:2 (1:0) | ||
| V | Shakhtar Donetsk | - | Lille | 0:0 (0:0) | ||
| I: 15.02.2006 19:00 | V: 23.02.2006 18:00 | Campeones: Lille | ||||
| I | Rosenborg BK | - | Zenit | 0:2 (0:2) | ||
| V | Zenit | - | Rosenborg BK | 2:1 (0:1) | ||
| I: 15.02.2006 19:30 | V: 23.02.2006 18:00 | Campeones: Zenit | ||||
| I | Schalke | - | Espanyol | 2:1 (0:1) | ||
| V | Espanyol | - | Schalke | 0:3 (0:0) | ||
| I: 15.02.2006 20:00 | V: 23.02.2006 21:45 | Campeones: Schalke | ||||
| I | sc Heerenveen | - | FC Steaua Bucureşti | 1:3 (1:1) | ||
| V | FC Steaua Bucureşti | - | sc Heerenveen | 0:1 (0:0) | ||
| I: 15.02.2006 20:30 | V: 23.02.2006 18:00 | Campeones: FC Steaua Bucureşti | ||||
| I | Bolton Wanderers | - | Marsella | 0:0 (0:0) | ||
| V | Marsella | - | Bolton Wanderers | 2:1 (1:1) | ||
| I: 15.02.2006 20:45 | V: 23.02.2006 20:45 | Campeones: Marsella | ||||
| I | Udinese | - | RC Lens | 3:0 (1:0) | ||
| V | RC Lens | - | Udinese | 1:0 (0:0) | ||
| I: 15.02.2006 20:45 | V: 23.02.2006 20:45 | Campeones: Udinese | ||||
| I | Club Brugge KV | - | Roma | 1:2 (0:1) | ||
| V | Roma | - | Club Brugge KV | 2:1 (0:0) | ||
| I: 15.02.2006 20:45 | V: 23.02.2006 21:00 | Campeones: Roma | ||||
| I | Betis | - | AZ Alkmaar | 2:0 (0:0) | ||
| V | AZ Alkmaar | - | Betis | 2:1 (2:0, 2:0) pró. | ||
| I: 15.02.2006 21:30 | V: 23.02.2006 20:45 | Campeones: Betis | ||||
| I | FC Thun | - | Hamburgo | 1:0 (1:0) | ||
| V | Hamburgo | - | FC Thun | 2:0 (2:0) | ||
| I: 16.02.2006 18:30 | V: 23.02.2006 18:30 | Campeones: Hamburgo | ||||
| I | Stuttgart | - | Middlesbrough | 1:2 (0:1) | ||
| V | Middlesbrough | - | Stuttgart | 0:1 (0:1) | ||
| I: 16.02.2006 20:45 | V: 23.02.2006 20:45 | Campeones: Middlesbrough | ||||
| I | Slavia Praga | - | Palermo | 2:1 (1:1) | ||
| V | Palermo | - | Slavia Praga | 1:0 (0:0) | ||
| I: 16.02.2006 20:45 | V: 23.02.2006 16:00 | Campeones: Palermo | ||||
